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Chapter 1 - Nanoelectrochemistry at the liquid/liquid interfaces

Identifieur interne : 004516 ( Main/Exploration ); précédent : 004515; suivant : 004517

Chapter 1 - Nanoelectrochemistry at the liquid/liquid interfaces

Auteurs : Shigeru Amemiya [États-Unis] ; Yixian Wang [États-Unis] ; Michael V. Mirkin [États-Unis]

Source :

RBID : ISTEX:DCBBD462566D910B1D6CFC7C7798E579A9CD55FC

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English descriptors

Abstract

Heterogeneous charge-transfer (CT) reactions and electrocatalytic processes occurring at the interface between two immiscible electrolyte solutions (ITIES), are central to many biological and technological systems. A prominent current trend is to study such processes at nanometer-sized interfaces. The ITIES supported at the tip of a nanopipet can also be used as a tip in the scanning electrochemical microscope (SECM) to carry out kinetic experiments and high-resolution imaging. This review is focused on new challenges and opportunities stemming from the use of nanoelectrochemical approaches. The surveyed applications include mechanistic studies of CT reactions and nanoparticle electrocatalysis, electrochemical imaging and sensing.

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DOI: 10.1039/9781849737333-00001


Affiliations:


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<term>Nanotip</term>
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<term>Quartz</term>
<term>Rate constants</term>
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<term>Shao</term>
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<term>Steady state</term>
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<term>Theoretical curves</term>
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<term>Approach curve</term>
<term>Approach curves</term>
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<term>Electrochemical</term>
<term>Electrochemistry</term>
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<term>Feedback</term>
<term>Free ionophore</term>
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<term>Inert substrate</term>
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<term>Inner solution</term>
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<term>Interface</term>
<term>Ionophore</term>
<term>Ities</term>
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<term>Kinetic measurements</term>
<term>Kinetic parameters</term>
<term>Kinetic study</term>
<term>Kinetics</term>
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<term>Lling</term>
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<term>Macroscopic ities</term>
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<term>Mass transport</term>
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<term>Negative feedback response</term>
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<term>Pipet radius</term>
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<term>Potassium transfer</term>
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<term>Quartz</term>
<term>Rate constants</term>
<term>Redox</term>
<term>Redox species</term>
<term>Samec</term>
<term>Scanning electrochemical microscopy</term>
<term>Secm</term>
<term>Secm imaging</term>
<term>Second phase</term>
<term>Shao</term>
<term>Simple transfers</term>
<term>Smaller pipets</term>
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<term>Spatial resolution</term>
<term>Steady state</term>
<term>Tcnq</term>
<term>Theoretical curves</term>
<term>Thermal drift</term>
<term>Topography imaging</term>
<term>Voltammetric</term>
<term>Voltammetry</term>
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<front>
<div type="abstract">Heterogeneous charge-transfer (CT) reactions and electrocatalytic processes occurring at the interface between two immiscible electrolyte solutions (ITIES), are central to many biological and technological systems. A prominent current trend is to study such processes at nanometer-sized interfaces. The ITIES supported at the tip of a nanopipet can also be used as a tip in the scanning electrochemical microscope (SECM) to carry out kinetic experiments and high-resolution imaging. This review is focused on new challenges and opportunities stemming from the use of nanoelectrochemical approaches. The surveyed applications include mechanistic studies of CT reactions and nanoparticle electrocatalysis, electrochemical imaging and sensing.</div>
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